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  • 向少华

    研究副教授(硕士生导师）
    • 邮箱：xiangsh@sustech.edu.cn
    办公室：南方科技大学慧园6栋301室
    个人主页：
    http://faculty.sustech.edu.cn/xiangsh/


    • 基本介绍
    • 研究方向
    • 学术成果
    • 其它信息
    教育背景：
    2010.08—2014.07        南洋理工大学（新加坡） 博士
    2006.09—2009.12        厦门大学 硕士
    2002.09—2006.06        厦门大学 学士

    工作经历：
    2024.10—今              南方科技大学深圳格拉布斯研究院 研究副教授
    2017.09—2024.09      南方科技大学前沿与交叉科学研究院 研究助理教授、研究副教授
    2015.02—2017.09      深圳华大基因研究院 产品经理

    荣誉及奖励：
    广东省杰出青年基金（2024年）
    轴手性化学，不对称有机催化
    1.Shi-Jiang He, Boming Shen, Lian-Zheng Zuo, Shao-Hua Xiang*, Huan-Huan Liu, Peiyuan Yu*, Bin Tan*. Enantioselective construction of anthracenylidene-based axial chirality by asymmetric Heck reaction. J. Am. Chem. Soc. 2024, 146, 19137.
    2.Shao-Hua Xiang, Wei-Yi Ding*, Yong-Bin Wang, Bin Tan*. Catalytic atroposelective synthesis. Nat. Catal. 2024, 7, 483-498.
    3.Peng-Ying Jiang, San Wu, Guan-Jun Wang, Shao-Hua Xiang*, Bin Tan*. Synthesis of axially chiral QUINAP derivatives by ketone-catalyzed enantioselective oxidation. Angew. Chem. Int. Ed. 2023, 62, e202309272.
    4.Jun Wei, Jian Zhang, Jun Kee Cheng, Shao-Hua Xiang*, Bin Tan*. Modular enantioselective access to β-amino amides by Brønsted acid-catalyzed multicomponent reactions. Nat. Chem. 2023, 15, 647.
    5.Xu-Jie Wang, Huan-Huan Liu, Jun Kee Cheng, Shao-Hua Xiang*, Bin Tan*. Catalytic enantioselective synthesis of chiral sulfonium ylides with S-stereogenic center. Chem 2023, 9, 1495.
    6.Shi-Jiang He, Shuai Zhu, Sheng-Qi Qiu, Wei-Yi Ding*, Jun Kee Cheng, Shao-Hua Xiang*, Bin Tan*. Phosphoric acid-catalyzed enantioselective synthesis of axially chiral anthrone-based compounds. Angew. Chem. Int. Ed. 2023, 62, e202213914.
    7.Shao-Hua Xiang†, Jun Kee Cheng†, Bin Tan*. The application of 2-naphthols in asymmetric synthesis of atropisomers. Synlett 2022, 33, 1991.
    8.Zhiqiang Lu*, Yanzhi Li, Shao-Hua Xiang*, Mengke Zuo, Yangxing Sun, Xingxing Jiang, Rongkai Jiao, Yinghong Wang, Yuqin Fu. Acid catalyzed stereocontrolled Ferrier-type glycosylation assisted by perfluorinated solvent. Molecules 2022, 27, 7234.
    9.Jun Kee Cheng†, Shao-Hua Xiang†, Bin Tan*. Organocatalytic enantioselective synthesis of axially chiral molecules: development of strategies and skeletons. Acc. Chem. Res. 2022, 55, 2920.
    10.Wei-Yi Ding, Huan-Huan Liu, Jun Kee Cheng, Hui Yao*, Shao-Hua Xiang*, Bin Tan. Palladium catalyzed decarboxylative β-C-glycosylation of glycals with oxazol-5-(4H)-ones as acceptors. Org. Chem. Front. 2022, 9, 6149.
    11.Wei-Yi Ding, Hao-Wen Zhao, Jun Kee Cheng, Zhiqiang Lu*, Shao-Hua Xiang*, Bin Tan. β-C-glycosylation with 2-oxindole acceptors via palladium-catalyzed decarboxylative reactions. Org. Lett. 2022, 24, 7031.
    12.Shuai Zhu, Jian-Hui Mao, Jun Kee Cheng, Shao-Hua Xiang*, Bin Tan*. Discovery and organocatalytic enantioselective construction of axially chiral cyclohexadienylidene skeletons. Chem 2022, 8, 2529.
    13.San Wu†, Shao-Hua Xiang†, Jun Kee Cheng*, Bin Tan*. Axially chiral alkenes: Atroposelective synthesis and applications. Tetrahedron Chem 2022, 1, 100009.
    14.Wang Xia, Zi-An Zhou, Jie Lv, Shao-Hua Xiang*, Yong-Bin Wang, Bin Tan*. Facile synthesis of N-aryl phenothiazines and phenoxazines via Brønsted acid catalyzed C–H amination of arenes. Chem. Commun. 2022, 58, 1613.
    15.Junxian Yang, Ji-Wei Zhang, Wen Bao, Sheng-Qi Qiu, Shaoyu Li, Shao-Hua Xiang*, Jun Song, Junmin Zhang*, Bin Tan*. Chiral phosphoric acid-catalyzed remote control of axial chirality at boron–carbon bond. J. Am. Chem. Soc. 2021, 143, 12924.
    16.Song Chen, Ya-Nan Li, Shao-Hua Xiang*, Shaoyu Li*, Bin Tan*. Electrochemical phenothiazination of naphthylamines and its application in photocatalysis. Chem. Comm. 2021, 57, 8512.
    17.Bing-Chao Da†, Shao-Hua Xiang†, Shaoyu Li, Bin Tan*. Chiral phosphoric acid catalyzed asymmetric synthesis of axially chiral compounds. Chin. J. Chem. 2021, 39, 1787.
    18.Ji-Wei Zhang, Shao-Hua Xiang*, Shaoyu Li, Bin Tan*. Copper-catalyzed synthesis of axially chiral biaryls with diaryliodonium salts as arylation reagents. Molecules 2021, 26, 3223.
    19.Shaoyu Li, Shao-Hua Xiang*, Bin Tan*. Chiral phosphoric acid creates promising opportunities for enantioselective photoredox catalysis. Chin. J. Chem. 2020, 38, 213.
    20.Shao-Hua Xiang, Bin Tan*. Advances in asymmetric organocatalysis over the last 10 years. Nat. Commun. 2020, 11, 3786.
    21.Ye-Hui Chen, Heng-Hui Li, Xiao Zhang, Shao-Hua Xiang*, Shaoyu Li, Bin Tan*. Organocatalytic enantioselective synthesis of atropisomeric aryl-p-quinones: Platform molecules for diversity-oriented synthesis of biaryldiols. Angew. Chem. Int. Ed. 2020, 59, 11374.
    22.Yong-Bin Wang, Quan-Hao Wu, Zhi-Peng Zhou, Shao-Hua Xiang*, Yuan Cui, Peiyuan Yu, Bin Tan*. Asymmetric construction of axially chiral 2-arylpyrroles by chirality transfer of atropisomeric alkenes. Angew. Chem. Int. Ed. 2019, 58, 13443.
    23.Lin-Lin Zhang, Bing-Chao Da, Shao-Hua Xiang*, Shuai Zhu, Zi-Yun Yuan, Zhen Guo*, Bin Tan*. Organocatalytic double arylation of 3-isothiocyanato oxindoles: stereocontrolled synthesis of complex spirooxindoles. Tetrahedron 2019, 75, 1689.
    24.Lin-Lin Zhang, Ji-Wei Zhang, Shao-Hua Xiang*, Zhen Guo*, Bin Tan*. Stereoselective construction of complex spirooxindoles via bisthiourea catalyzed three-component reactions. Chin. J. Chem. 2018, 36, 1182.

向少华研究副教授(硕士生导师）

邮箱：xiangsh@sustech.edu.cn
办公室：南方科技大学慧园6栋301室
个人主页：
http://faculty.sustech.edu.cn/xiangsh/


  • 基本介绍
  • 研究方向
  • 代表性论文
  • 其它信息
教育背景：
2010.08—2014.07        南洋理工大学（新加坡） 博士
2006.09—2009.12        厦门大学 硕士
2002.09—2006.06        厦门大学 学士

工作经历：
2024.10—今              南方科技大学深圳格拉布斯研究院 研究副教授
2017.09—2024.09      南方科技大学前沿与交叉科学研究院 研究助理教授、研究副教授
2015.02—2017.09      深圳华大基因研究院 产品经理

荣誉及奖励：
广东省杰出青年基金（2024年）
轴手性化学，不对称有机催化
1.Shi-Jiang He, Boming Shen, Lian-Zheng Zuo, Shao-Hua Xiang*, Huan-Huan Liu, Peiyuan Yu*, Bin Tan*. Enantioselective construction of anthracenylidene-based axial chirality by asymmetric Heck reaction. J. Am. Chem. Soc. 2024, 146, 19137.
2.Shao-Hua Xiang, Wei-Yi Ding*, Yong-Bin Wang, Bin Tan*. Catalytic atroposelective synthesis. Nat. Catal. 2024, 7, 483-498.
3.Peng-Ying Jiang, San Wu, Guan-Jun Wang, Shao-Hua Xiang*, Bin Tan*. Synthesis of axially chiral QUINAP derivatives by ketone-catalyzed enantioselective oxidation. Angew. Chem. Int. Ed. 2023, 62, e202309272.
4.Jun Wei, Jian Zhang, Jun Kee Cheng, Shao-Hua Xiang*, Bin Tan*. Modular enantioselective access to β-amino amides by Brønsted acid-catalyzed multicomponent reactions. Nat. Chem. 2023, 15, 647.
5.Xu-Jie Wang, Huan-Huan Liu, Jun Kee Cheng, Shao-Hua Xiang*, Bin Tan*. Catalytic enantioselective synthesis of chiral sulfonium ylides with S-stereogenic center. Chem 2023, 9, 1495.
6.Shi-Jiang He, Shuai Zhu, Sheng-Qi Qiu, Wei-Yi Ding*, Jun Kee Cheng, Shao-Hua Xiang*, Bin Tan*. Phosphoric acid-catalyzed enantioselective synthesis of axially chiral anthrone-based compounds. Angew. Chem. Int. Ed. 2023, 62, e202213914.
7.Shao-Hua Xiang†, Jun Kee Cheng†, Bin Tan*. The application of 2-naphthols in asymmetric synthesis of atropisomers. Synlett 2022, 33, 1991.
8.Zhiqiang Lu*, Yanzhi Li, Shao-Hua Xiang*, Mengke Zuo, Yangxing Sun, Xingxing Jiang, Rongkai Jiao, Yinghong Wang, Yuqin Fu. Acid catalyzed stereocontrolled Ferrier-type glycosylation assisted by perfluorinated solvent. Molecules 2022, 27, 7234.
9.Jun Kee Cheng†, Shao-Hua Xiang†, Bin Tan*. Organocatalytic enantioselective synthesis of axially chiral molecules: development of strategies and skeletons. Acc. Chem. Res. 2022, 55, 2920.
10.Wei-Yi Ding, Huan-Huan Liu, Jun Kee Cheng, Hui Yao*, Shao-Hua Xiang*, Bin Tan. Palladium catalyzed decarboxylative β-C-glycosylation of glycals with oxazol-5-(4H)-ones as acceptors. Org. Chem. Front. 2022, 9, 6149.
11.Wei-Yi Ding, Hao-Wen Zhao, Jun Kee Cheng, Zhiqiang Lu*, Shao-Hua Xiang*, Bin Tan. β-C-glycosylation with 2-oxindole acceptors via palladium-catalyzed decarboxylative reactions. Org. Lett. 2022, 24, 7031.
12.Shuai Zhu, Jian-Hui Mao, Jun Kee Cheng, Shao-Hua Xiang*, Bin Tan*. Discovery and organocatalytic enantioselective construction of axially chiral cyclohexadienylidene skeletons. Chem 2022, 8, 2529.
13.San Wu†, Shao-Hua Xiang†, Jun Kee Cheng*, Bin Tan*. Axially chiral alkenes: Atroposelective synthesis and applications. Tetrahedron Chem 2022, 1, 100009.
14.Wang Xia, Zi-An Zhou, Jie Lv, Shao-Hua Xiang*, Yong-Bin Wang, Bin Tan*. Facile synthesis of N-aryl phenothiazines and phenoxazines via Brønsted acid catalyzed C–H amination of arenes. Chem. Commun. 2022, 58, 1613.
15.Junxian Yang, Ji-Wei Zhang, Wen Bao, Sheng-Qi Qiu, Shaoyu Li, Shao-Hua Xiang*, Jun Song, Junmin Zhang*, Bin Tan*. Chiral phosphoric acid-catalyzed remote control of axial chirality at boron–carbon bond. J. Am. Chem. Soc. 2021, 143, 12924.
16.Song Chen, Ya-Nan Li, Shao-Hua Xiang*, Shaoyu Li*, Bin Tan*. Electrochemical phenothiazination of naphthylamines and its application in photocatalysis. Chem. Comm. 2021, 57, 8512.
17.Bing-Chao Da†, Shao-Hua Xiang†, Shaoyu Li, Bin Tan*. Chiral phosphoric acid catalyzed asymmetric synthesis of axially chiral compounds. Chin. J. Chem. 2021, 39, 1787.
18.Ji-Wei Zhang, Shao-Hua Xiang*, Shaoyu Li, Bin Tan*. Copper-catalyzed synthesis of axially chiral biaryls with diaryliodonium salts as arylation reagents. Molecules 2021, 26, 3223.
19.Shaoyu Li, Shao-Hua Xiang*, Bin Tan*. Chiral phosphoric acid creates promising opportunities for enantioselective photoredox catalysis. Chin. J. Chem. 2020, 38, 213.
20.Shao-Hua Xiang, Bin Tan*. Advances in asymmetric organocatalysis over the last 10 years. Nat. Commun. 2020, 11, 3786.
21.Ye-Hui Chen, Heng-Hui Li, Xiao Zhang, Shao-Hua Xiang*, Shaoyu Li, Bin Tan*. Organocatalytic enantioselective synthesis of atropisomeric aryl-p-quinones: Platform molecules for diversity-oriented synthesis of biaryldiols. Angew. Chem. Int. Ed. 2020, 59, 11374.
22.Yong-Bin Wang, Quan-Hao Wu, Zhi-Peng Zhou, Shao-Hua Xiang*, Yuan Cui, Peiyuan Yu, Bin Tan*. Asymmetric construction of axially chiral 2-arylpyrroles by chirality transfer of atropisomeric alkenes. Angew. Chem. Int. Ed. 2019, 58, 13443.
23.Lin-Lin Zhang, Bing-Chao Da, Shao-Hua Xiang*, Shuai Zhu, Zi-Yun Yuan, Zhen Guo*, Bin Tan*. Organocatalytic double arylation of 3-isothiocyanato oxindoles: stereocontrolled synthesis of complex spirooxindoles. Tetrahedron 2019, 75, 1689.
24.Lin-Lin Zhang, Ji-Wei Zhang, Shao-Hua Xiang*, Zhen Guo*, Bin Tan*. Stereoselective construction of complex spirooxindoles via bisthiourea catalyzed three-component reactions. Chin. J. Chem. 2018, 36, 1182.